Studying of Catalyst Deactivation in a Commercial Hydrocracking Process (ISOMAX)

Hydrocracking Lumped Kinetic Model with Catalyst Deactivation in Arak Refinery Hydrocracker Unit

A kinetic model of a fixed bed tubular reactor incorporating catalyst deactivation was developed for the ISOMAX unit of Arak refinery. The kinetic parameters for the hydrocracking reactions over the commercial catalyst were determined using initial activity plant data i.e. when the catalyst is fresh. Catalyst deactivation was then taken into account by means of deactivation function based on pl...

Catalyst deactivation

The fundamentals of catalyst deactivation are presented in this review. The chemico-physical aspects concerning the various deactivation causes (i.e. poisoning, sintering, coking, solid-state transformation, masking, etc.) have been analyzed and discussed, along with the mathematical description of the deactivation phenomena. # 1999 Elsevier Science B.V. All rights

Heterogeneous Catalyst Deactivation and Regeneration: A Review

Deactivation of heterogeneous catalysts is a ubiquitous problem that causes loss of catalytic rate with time. This review on deactivation and regeneration of heterogeneous catalysts classifies deactivation by type (chemical, thermal, and mechanical) and by mechanism (poisoning, fouling, thermal degradation, vapor formation, vapor-solid and solid-solid reactions, and attrition/crushing). The key...

Determination of the Deactivation Model of Iron-potassium/γ-Al2O3 Catalyst in a Fixed Bed Reactor

Catalyst activity and performance are the most important factors for selecting a catalyst in different processes. The Fischer-Tropsch synthesis is a very important synthesis that extensive action has been taken place to increase the activity of its catalysts in the recent century. Deactivation of the catalysts of the process is influenced by many factors, among which coking and sintering have c...

Advances in Catalyst Deactivation and Regeneration

Optimizing the vacuum gas oil hydrocracking process temperature in the presence of Ni-Mo/γ-Al2O3-SiO2 catalyst

A suitable model for predicting the product quality of vacuum gas oil (VGO) catalytic hydrocracking is developed. Data were obtained using an experimental catalytic hydrocracking reactor loaded with the Ni-Mo/Al2O3-SiO2 catalyst. A set of experimental runs was conducted under various operating temperatures from 380 to 450 ℃. Three distribution models were used t...